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Phenol, a health hazardous agent due to its high reactivity 52 was detected at low levels ( 1.5 (Supplementary Spreadsheet S1) as revealed from OPLS-DA that are characteristic to tobacco cigarette and have the potential to discriminate it from hookah tobacco products include: Furfuryl alcohol, ()-solanone, dihydrocarvyl acetate, 5-methylfurfural, nicotine, furfural, nitrosoazetidine, 3-furaldehyde, (Z) -3-hexenyl heptanoate, geranyl acetone, hedione (methyl dihydrojasmonate), piperonal, (Z) --hexenyl caproate, -ionone, and geraniol butyrate