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1 H-fMRS processing Data were preprocessed using an automated Free Induction Decay Appliance (FID-A) pipeline, which includes coil combination, removal of motion corrupted scans and spectral registration for frequency and phase drift correction 67,68

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Conformational Search and ECD Spectra Simulation The conformational search of GHRPs was performed by the conformerrotamer sampling tool (CREST) [25, 26] with the GFN2xTB method [27] and implicit solvation considered by the analytical linearized PoissonBoltzmann (ALPB) model [28]