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But even though the effectiveness of FDA-approved, pharmaceutical nicotine-based medications for smoking cessation is much more modest than the manufacturers claim, they have an established, potentially harm-reducing role as an adjunct to the reinforcing, behavior-modifying messages of health care professionals, health organizations, and the mass media

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The emergence of these regions of partial charge about both molecules provide sites for solute anions to be attracted to the polarised hydrogen, and cations to the lone pair about the oxygen, overcoming the solute-solute attractive forces of the other molecules - particularly the nicotine salt