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Compounds have to be airborne in order for our nose to be able to detect their smell, so it follows that any compounds that are particularly large (for example, the melanoidins that contribute to coffees colouration) will have low volatilities, and wont contribute to the aroma

According to a history of the Bull Durham Tobacco Company, W.T

Lighting Seeing flies near lighting is something you are probably familiar with, especially in the evenings when more lights in your house are likely to be switched on